Chapter 2 Solids

Liquids can be cooled to form a solid, a state of matter where the particles are generally fixed into a particular position. Solids can be crystalline where the particles are arranged in a definite, repeatable, and orderly pattern or amorphous where the particles lack long-range order (i.e. has no repeating patterns) as seen with glass, rubber, many polymers, pitch, and more.

Ordered arrangement of particles in a crystalline solid.

Figure 2.1: Ordered arrangement of particles in a crystalline solid.

Disordered arrangement of particles in an amorphous solid.

Figure 2.2: Disordered arrangement of particles in an amorphous solid.

Solids can be characterized into various types, each exhibiting a set of properties.

Type Particles Attractions Properties Examples
ionic ions ionic hard, brittle, conducts electricity as a liquid but not as a solid, high to very high melting points NaCl, Al2O3
metallic atoms of electropositive elements metallic shiny, malleable, ductile, conducts heat and electricity well, variable hardness and melting points Cu, Fe, Ti, Pb, U
covalent network atoms of electronegative elements covalent very hard, not conductive, very high melting points C (diamond), SiO2, SiC
molecular molecules (or atoms) IMFs variable hardness, variable brittleness, not conductive, low melting points H2O, CO2, I2, C12H22O11